The Basics of Inorganic Glasses – Properties, Types, and Structure

Introduction

Inorganic glass is an amorphous, hard, brittle, transparent, and super-cooled liquid of infinite viscosity. It is manufactured by fusing a mixture of number of metallic silicates.

The term Inorganic is added with glass because a glass is a mixture of inorganic compounds such as silicates of sodium, potassium, calcium, and lead. Only a few metallic carbonates are used for manufacturing. Although carbonates have only a little amount of carbon, carbonates of metals are studied in inorganic science. Organic compounds are not used for manufacturing any type of glass; therefore, it is called inorganic glass.

Structure of Fundamental Inorganic Glasses

The structure fundamental inorganic glass is xR2O.yMO.6SiO2, where R is an atom of monovalent alkali metals such as Na, K, etc. and M is an atom of a bivalent metal such as Ca, Pb, Zn etc., and x and y are whole numbers.

General Properties of Inorganic Glass

  • It is amorphous in nature.
  • It has no definite melting point.
  • It can absorb, reflect, and transmit light.
  • It can take a high polish.
  • It is a good electrical insulator.
  • It is affected by alkalis.
  • It is not affected by air, water, or acids or chemical reagents except HF. When it reacts with HF, the silicate component of inorganic glass converts to SiF4.
  • It can be formed into different articles; even it can be formed in complex shapes.
  • It is brittle in nature.
  • It is softened by heating.
  • It is light in weight with respect to the volume or size. This is because it has a homogeneous internal structure.
  • It does not have a crystal structure; due to this, it has a high compressive strength.

Different Steps of Manufacturing Inorganic Glass

Different types of inorganic glasses are manufactured by four steps described below:

  • Melting

This is the process of melting raw material in proper proportions. First of all, raw materials are mixed with cullets for powdering. The powdered mixture is then sent for fusing. For fusing the mixture, different chambers are used regarding different purposes such as fireclay pots used for making high-grade glass, and tanks (a part of open- hearth furnaces) are used for low-grade glasses. The mixture melts and fuses at high temperature, about 1800 0C.

  • Forming and Shaping

Molten glass is then converted into desired shape either by molding or by pressing between rollers.

  • Annealing

Glass articles are then allowed to pass through different chambers having different temperatures, but the chambers are placed in descending order of temperature. This is designed to cool glass articles nearly to room temperature.

The glass article cannot cool rapidly because inorganic glass is a bad conductor of heat. When the article is rapidly cooled, then the superficial layer cools down first and the interior part gets high strain and the article breaks into pieces.

  • Finishing

After the annealing process all glass articles are subjected to perform different finishing processes such as cleaning, grinding, polishing, cutting, and sand-blasting.

References

Reference: Engineering Chemistry-Jain.Jain
Image: flickr.comSalva Del Saz -The Glassy Prow
Image: Flickr.comflyingsourcers– Glass Pane

Types of Inorganic Glasses- Composition, Properties, and Uses

The fundamental types of glasses are given below

  • Soda-lime or Soft Glass

Composition- Na2O.CaO.6SiO2

Properties- They are low in cost, resistant to water, and can melt easily.

Uses- Used as windows glass, plate glasses, electric bulbs, bottles, jars, and building materials.

  • Potash-lime or Hard Glass

Composition- K2O.CaO.6SiO2

Properties-They have high melting point, fuse with difficulty, and are less affected by acids, alkalis and other solvents.

Uses- Used for chemical apparatus and combustion tubes.

  • Lead Glass or Flint Glass

Composition- K2O.PbO.6SiO2

Properties- They are more expensive than lime-soda glass but easier to shape and work with.

Uses- Used for high quality tableware and optical purposes.

Glass Pane

Other Inorganic Glasses Based on Fundamental Glasses

The above glasses are the fundamental glasses. The types of glasses given below are manufactured using these fundamental glasses.

  • Pyrex Glass or Jean Glass

Composition- These glasses contain virtually only silica and boron, with a small amount of aluminum and some alkali oxides.

Properties- They have low thermal coefficient of expansion, high chemical resistance very high softening point and high resistivity.

Uses- Used in industries of pipe lines, gauge glasses, superior laboratory glasses, kitchenware, chemical plants, and television tubes.

  • Aluminosilicate Glass

Composition- they are made up of mainly aluminum and silica, with a small amount of boron and alkalis oxides.

Properties- They have comparatively high softening temperature.

Uses- Used for high mercury discharge tubes, chemical combustion tubes, domestic equipment.

  • 99.5% Silica or Vitreosil

Composition- It is produced by heating pure sand, i.e. SiO2 (quartz)

Properties- They have high viscosity, shaping is difficult, and the thermal expansion is low.

Uses- Used for chemical plants, chemical laboratory wares, electrical insulating materials in electric heaters, furnaces.

  • Optical or Crooks Glass

Composition- It contains phosphorous and lead silicate, together with cerium oxide.

Properties- They are capable of absorbing ultraviolet rays, have low melting point, and are relatively soft.

Uses- Used for making lenses.

  • Insulating Glass

Composition- They are made by using two or more plates of glass separated by 6 to 13 mm thick gap, filled up with dehydrated air.

Properties- They are transparent units and provide high insulation against heat.

Uses- Used for separating apartments.

Inorganic Glasses manufactured by adding organic Components

There are also some new types of glasses those are manufactured by adding organic components. A few of them are as follows:

  • Laminated Glass

Composition- They are made by bonding together two or more sheets of glass with one or more alternate layer of bonding material such as plastic resin, asphalt, or synthetic rubber.

Properties- This glass is shatter proof and shock proof.

Uses- Used as safety glasses for automobiles, airplanes, helicopters, and submarines.

  • Safety Glass

Composition- Made by taking 2 or 3 glass sheets and adding alternate thin layer of vinyl plastic.

Properties- It is tougher than any other glass.

Uses- Used for automobile and airplane industries as wind shields.

  • Toughened Glass

Composition- They are made by dipping the hot article in an oil tank. This process makes the outer layer of article shrink and acquire a state of compression, while the inner layer remains tensioned.

Properties- They are more elastic and they can absorb for mechanical and thermal shock.

Uses- Used for window shields for fast moving vehicles, window shields for furnaces, automatic doors, and large show-cases

References

Reference: Engineering Chemistry-Jain.Jain
Image: flickr.comSalva Del Saz -The Glassy Prow
Image: Flickr.comflyingsourcers– Glass Pane